Search results for "CO2 utilization"

showing 2 items of 2 documents

An Investigation into the Stability of Graphitic C 3 N 4 as a Photocatalyst for CO 2 Reduction

2018

The increasing CO 2 concentration in the atmosphere exerts a significant influence on global warming and climate change. The capture and utilization of CO 2 by conversion to useful products is an area of active research. In this work, the photodriven reduction of CO 2 was investigated using graphitic carbon nitride (g-C 3 N 4 ) as a potential photocatalyst. The photocatalytic reduction of CO 2 was investigated with g-C 3 N 4 powder immobilized on a glass support in a batch gas-phase photoreactor. The experiments were carried out under UV-vis irradiation at 70 °C and an initial pressure of 2.5 bar. The only gas-phase product detected during the irradiation of the g-C 3 N 4 in the presence of…

Materials scienceCO2 carbon nitride02 engineering and technology010402 general chemistry01 natural sciencesReduction (complexity)chemistry.chemical_compoundCo2 concentrationco2 utilizationIrradiationPhysical and Theoretical ChemistryCo generationElectronic Optical and Magnetic MaterialGraphitic carbon nitride021001 nanoscience & nanotechnologyphotochemical membrane reactor0104 chemical sciencesElectronic Optical and Magnetic MaterialsSurfaces Coatings and FilmsGeneral EnergyEnergy (all)chemistryChemical engineeringPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyBar (unit)
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CO2 reduction by C3N4-TiO2 Nafion photocatalytic membrane reactor as a promising environmental pathway to solar fuels

2019

Abstract We investigated CO2 photocatalytic reduction coupling, for the first time in literature, the assets offered by the continuous operating mode using C3N4-TiO2 photo-catalyst embedded in a dense Nafion matrix. The reactor performance was analyzed under UV–vis light in terms of productivity, selectivity and converted carbon. Reaction pressure was specifically investigated for its effect as a “driver” in determining reactor performance, modulating products removal from the reaction volume. In addition, the membrane reactor performance was explored as a function of H2O/CO2 feed molar ratio and contact time. The higher feed pressure (5 bar) led to a lesser MeOH production and a greater am…

Materials sciencesolar fuels2utilizationchemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundNafionDesorptionPartial oxidationGeneral Environmental ScienceMembrane reactorProcess Chemistry and Technologytechnology industry and agriculture021001 nanoscience & nanotechnology0104 chemical sciencesCOSolar fuelchemistryChemical engineeringVolume (thermodynamics)Settore CHIM/03 - Chimica Generale E InorganicaPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologySelectivityCarbonCO2 utilizationCO2 utilization Solar fuel
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